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In an aqueous solution, the reducing agents generally generate one or more compounds comprising an aldehyde group.The reducing sugars can be oxidized with some relatively mild oxidizing agents such as salts of metals.The reducing sugar mostly forms a hemiacetal structure where a carbon gets attached to a couple of oxygen atoms thus resulting in the formation of either ether or alcohol.The reducing sugars such as glucose and fructose have a free aldehyde group and ketone in their structures, respectively.Some of the most significant characteristics of reducing sugar have been summarized in the points below. The reducing sugar is also mentioned as the compounds such as sugar or an element, for instance, calcium that lose an electron to another chemical or biological species in the reactions stated as the oxidation-reduction (often abbreviated as the redox reactions). The most common examples of reducing sugar are maltose, lactose, gentiobiose, cellobiose, and melibiose while sucrose and trehalose are placed in the examples of non-reducing sugars.The reducing sugar can reduce the capric ions of the Fehling or the Benedict solution into the cuprous ions whereas, the reduction of cupric ions into the cuprous ions is not achieved in the non-reducing sugars.The reducing sugars are mainly monosaccharides where all polysaccharides are non-reducing sugars.The reducing sugar forms osazones while the other form of sugar doesn’t form osazones.The reducing sugars possess mutarotation while on the other hand, the non-reducing never exhibit such rotational behaviors.The non-reducing sugar form is in the acetal or the ketal form whereas the reducing forms are in the hemiketal or the hemiacetal.Reducing sugars are the carbohydrates with free aldehyde and the ketone group while in the non-reducing sugar, no such free groups are found rather, they are available in the formation of bonds. Key differences between reducing and non-reducing sugars: Is starch a reducing sugar? It should be remembered here that starch is a non-reducing sugar as it does not have any reducing group present. Figure 1: Chemical Structure of Glucose, Fructose, and Sucrose. Contrarily, maltose and lactose, which are the reducing sugar, have a free anomeric carbon that can get converted into an open-chain form by forming a bond with the aldehyde group. In sucrose, there are glycosidic bonds between their anomeric carbons to retain the cyclic form of sucrose, avoiding its conversion into the form of an open chain with an aldehyde group. Sucrose (glucose + fructose) lacks a free aldehyde or ketone group and therefore is non-reducing. Maltose (glucose + glucose) and lactose (galactose + glucose) have a free aldehyde group and thus are reducing sugars. Glucose, fructose, and galactose are monosaccharides and are all reducing sugars. Cellulose, starch, glycogen, and chitin are all polysaccharides examples. The three most common disaccharide examples are lactose, sucrose, and maltose. Relatively larger chains of sugar molecules that are interconnected with each other via chains are oligosaccharides and polysaccharides. Single sugar molecules (monomers) are the monosaccharides and the two monomers linked together are the disaccharides. These sugars are the carbohydrates that we often consume in our diet. The chemical configuration and structure of sugar particularly, glucose, fructose, and sucrose have been elaborated in Figure 1. The chemical formulation of sugar is C n (H 2O) n (e.g., C 6H 12O 6 for glucose), which is naturally found in all fruits, dairy products, vegetables, and whole grains. The most common example of ketose is fructose whereas glucose and galactose are aldoses. The structural isomers of the chemical compounds that can instantly interconvert are tautomers and the process in chemistry is referred to as tautomerization. It should be remembered here that before acting as the reducing agents, ketoses must tautomerize aldoses. The monosaccharides are categorized into two groups: (1) aldoses that contain the free aldehyde group and (2) ketoses where there is a ketone group. Some of the disaccharides, oligosaccharides, polysaccharides, and all monosaccharides are reducing sugars. Examples are glucose, fructose, glyceraldehydes, lactose, arabinose and maltose, except for sucrose. Reducing Sugar (biology definition): A sugar that serves as a reducing agent due to its free aldehyde or ketone functional groups in its molecular structure. Occasionally you can find modern model D's for sale that were used as hire pianos. However, they are rare on the market and most concert halls sell them once they have been well used. Used in many top concert halls and conservatories around the world. Steinway model D is the largest Steinway grand piano. More informationĭiscontinued in 1913 but is occasionally produced in Hamburg from 1923. A high-end square grand piano can cost anywhere between 65,000 and 190,000. The length makes for a clear tenor section and longer keys allow greater dynamic expression. The model B Steinway grand is an excellent piano suited for medium to large concert spaces or large domestic environments. Informationįormerly Manufactured in New York now manufactured in Hamburg from 1923. The Steinway model A is a resonant mid-sized Steinway grand. Recommended for medium to large sized domestic settings. Mainly old-styled ones available in the UK with fretted music desk and elephant legs. The A was the shortest model up to about 1900. This grand piano offers power and warmth, with a design that allows the solid spruce soundboard to freely and efficiently resonate, like its larger counterparts. Formerly manufactured in New York manufactured in Hamburg from about 1900. At 6 2' (188 cm), the Model A Salon Grand piano is known for delivering a grand sound in a medium-scale instrument. The model O is one of the most common Steinways available. A resonant mid-sized grand from the German manufacturer. Highly recommended for medium to mid-large sized rooms. Often available in rosewood or more modern polyester black. Steinway model M, also known as the "medium grand" is a common grand that we have in stock. The main competitor to the S is the 4ft 11in Bluthner model IV baby grand which is much more common. The rarest size of used Steinway out of 100 Steinways in the UK about one will be a model S. O5’10”1900 The Steinway model O is one of the more common models of Steinway in the UK. All budding pianists, of whatever age and whatever level of skill, should always have access to the best instruments available, and Roberts Pianos, whose instruments are superbly maintained, is in a unique position to help. I would also not hesitate in recommending his business to the amateur pianist as much as the professional. For my annual Oxford Summer Piano Series Marcus went out of his way to make sure I had a superb instrument on which to prepare 8 taxing recital programmes while visiting the city, and his help has been invaluable. He has shown the same care and attention to the need of the professional pianist as any of these famous names from the past. Oxford is really fortunate in having Marcus Roberts and Roberts Pianos. Beethoven and Broadwood, Chopin and Pleyel, Liszt and Bechstein, Gershwin and Steinway, Richter and Yamaha, etc.). For that reason there has always been a strong relation between pianists and piano makers, technicians and tuners (e.g. The whole and balanced sound is also very appreciated by professionals and enlightened amateurs.Unlike other instrumentalists who can carry their instruments with them, pianists are more reliant than most musicians on the people who maintain and care for the instrument. When it arrived in our store, attention was paid to the precision of the settings and the care of the furniture, to restore the instrument to its original shine. It has been the subject of a unique experimental adjustment work provided by the brand's specialists. Having belonged to a renowned individual, this Steinway piano has benefited from remarkable care and presents a piece of furniture in perfect condition. Special care given to this second-hand Steinway piano: This used piano benefits from the new Steinway patents, which its predecessors did not have, which will guarantee an incomparable playing pleasure. The preservation of its reference allows a reliable investment over time. The used M-170 model is a rare opportunity to host an instrument from the prestigious German brand. Its size allows it to easily fit into any interior. The Steinway & Sons M-170 dazzles with its richness of modulation, precision and wide spectrum of harmonic nuances. A stunning Gaveau Paris baby grand piano in an art deco two tone veneered case This piano dates from the early 1940s and was in an english country house for the last few. It easily finds its place in all types of interiors. It will surpass in sound other manufacturers, even for models of larger sizes. It is a quart-de-grand piano, which develops powerful and rich bass in a contained size (170 cm). Handcrafted since 1853, Steinway & Sons pianos benefit from all the know-how of the German firm, for an unparalleled rendering.ĭid you know that a Steinway upright piano requires more than six months of work before it can leave the factories in Hamburg and New York? A quarter-grand piano with a personal and inimitable character That means that a single premium user could have 50,000 songs downloaded at one time. Spotify allows premium users to download 10,000 songs on each of up to 5 different devices. Spotify Premium users have an extremely high limit on how many songs they can download. Spotify Download Limits for Premium Users You can also control how many devices you can have downloaded content on and how high the quality of the downloads will be. But if you are a premium member, then you can download any song, album, or playlist that you want for offline listening. You need to be a premium member of Spotify in order to download songs. No you can't download songs on Spotify's free version of their app. Join IFTTT today!Ĭan You Download Songs on Spotify's free version? IFTTT is a tool that lets you connect Spotify with everything else on the internet. That's all there is to it! Now you know how to download individual songs or even download albums on spotify so you can enjoy your music even when you're not connected to wifi. On that playlist homepage, you will see a down arrow which you can click to download the playlist to your device.Put all the songs you want to download in a special playlist.Find the song album or artist you want to download.Open Spotify on your desktop or mobile phone.A menu will pop up select "Download." The song will then start downloading once it's finished, you'll be able to listen to it without an internet connection. Once you've found it, tap the three dots next to the title. Then, find the song, album, or artist that you want to download. So whether you're on the bus, at the gym, or in another country altogether, your favorite tunes will always be with you!įirst, open the Spotify app on your device. In this blog post, we will teach you how to do just that. Spotify is a great way to listen to music, but what if you don't have wifi? No problem! You can download music and podcasts on Spotify so that you can listen to them offline. In general, apes that were good in one area-such as tests requiring creative tool use-were not necessarily good in another-such as copying the actions of a test-giver to get a reward, the team reports this week in the Philosophical Transactions of the Royal Society B. The researchers analyzed the data to determine if the scores in some tests helped predict performance in others. In another, they had to use a stick to get food placed on a high platform. In one experiment, chimps were asked to find food in a container after it had been shuffled around with empty containers. So they gave a battery of physical and social tests to 106 chimps at Ngamba Island and the Tchimpounga chimpanzee sanctuary in the Republic of the Congo, and to 23 captive chimpanzees and bonobos in Germany. During the study, they noticed a wide range of skills among the chimps and wondered whether they could measure this variation in ability-and whether there were studies that could predict the chimps’ overall performance in all areas, like an IQ test in humans. Herrmann and her colleagues had previously tested chimps in a study designed to compare the skills of the animals with those of human children. "Natasha was really much better than other chimps," says biologist and first author of the new study Esther Herrmann of the Max Planck Institute for Evolutionary Anthropology in Leipzig, Germany. There are two configurations for heptagrams the acute heptagram, shown here, and the obtuse heptagram. Seven-pointed stars are known as heptagrams or septagrams. Intersecting point-up and point-down triangles creates hexagrams. When paired and presented as point-to-point, triangles represent sexual union and the principle of harmony. Symbols for air and fire are formed from point-down triangles point-down triangles can represent the descent into the physical world. The point-down triangle can represent female energy, and water and earth are feminine elements. The point-up triangle can also represent male energy, and fire and air are masculine elements. Earth and water symbols are formed from point-up triangles pointing upward stands for the ascent to heaven. Point-up triangles represent a strong foundation or stability. The orientation of a triangle can be important to its meaning. The occultist often performs rituals from the protection of a circle. At the culmination of a ritual, the desired being is expected to appear within a triangle inscribed upon the floor. Some occultists use the triangle as a summoning symbol. Triangles and other three-part symbols may present such concepts as past, present, and future or spirit, mind, and body. Pythagoras associated the number 3 with triangles, which is meaningful to many groups. Because the Christian God is a trinity-Father, Son, and Holy Ghost united in a single godhead-he is commonly represented by a triangle. In Western society, equilateral triangles most often have Christian meanings in religious contexts. The element of spirit, seen as an element equal to or superior to the physical elements of fire, air, water, and earth, is commonly represented by a circle. The same symbol is used to represent gold, which is strongly associated with the sun. The astrological symbol of the sun is a circle with a dot in the middle. The circle is also used nearly universally to represent the sun and/or the moon, or things associated with those bodies. Ouroboros is also found in Aztec and Norse mythologies. First attested in the New Kingdom Egypt in the 10th-11th century BCE, the ouroboros represents the cycle of rebirth, completion, unification of polarities, regeneration, and eternity. The ouroboros (Greek for "tail swallower") is a circular symbol representing a snake or dragon feeding off its own tail, or two such creatures feeding off each other's tails. Circles can also represent containing, keeping what is inside from been released. In occult practices, standing within a circle shields people from supernatural dangers or outside influences. In Chinese symbology, the circle represents the heavens.Ĭircles are also often seen as protective symbols. Circles are sometimes symbols of the Judeo-Christian God and sanctity, appearing as haloes. In the Zen Buddhist philosophy, a circle stands for enlightenment and perfection in unity with the primal principles. He associated the circle with the number 1 and the practice of monotheism. Pythagoras called the circle "monad," the most perfect of creative forms, without beginning or end, without sides or corners. Circles are among the oldest of geometric symbols, and commonly represent unity, wholeness, and infinity. There were some, not many, but a few instances in which it could have been better. was kind of average, it wasn't the worst but it wasn't the best either. That's more or less the background story, with the show centered around the main male character who turns out to be one of the strongest with a harem of girls (more detailed in characters) The world is constantly under attack by monsters whom are fought by the said special users. The story itself is a good one, there are people who have memories of previous lives that they had and have special weapons and spells from it. Can those whose minds live in both the present and the past truly reach a bright future? Delve into the complex world of Seiken Tsukai no World Break to find out!Īs a veteran harem watcher, this anime isn't entirely original in its character personalities, however it made up for it with the story it has. Soon afterwards he meets another girl, Shizuno Urushibara, who eventually reveals that she also knew Moroha in an entirely different past life where he was a dark lord capable of using destructive magic but saved her from a life of slavery. After the ceremony is over, the main character, Moroha Haimura, meets a girl named Satsuki Ranjou who reveals that she was Moroha's little sister in a past life where Moroha was a heroic prince capable of slaying entire armies with his sword skills. The story begins six months prior to the major climax of the series during the opening ceremonies on the first day of the school year. Known as saviors, the students are broken up into two categories: the kurogane who are able to use their prana to summon offensive weapons and the kuroma who are able to use magic. Seiken Tsukai no World Break takes place at Akane Private Academy where students who possess memories of their previous lives are being trained to use Ancestral Arts so that they can serve as defenders against monsters, called Metaphysicals, who randomly attack. It devolved during our study, that while the main experiment is still considered to be the thermal convection experiment discussed in our original Expression of Interest, there are now a very substantial set of other, important and fundamental experiments which can be done with the large cryostat proposed for the convection experiment. The swelling in irradiated beryllium is attributed to the helium gas generated during irradiation. Lelio è lelemento chimico della tavola periodica che ha numero atomico 2 e simbolo He. Typical scientific issues to be addressed in the facility will be discussed. The proposed facility is possible only because of the advanced cryogenic technology available at the SSCL. The facility will be a unique national resource for studies of high-Reynolds-number and high-Rayleigh-number and high Rayleigh number turbulence phenomena, and is one of the six items determined as suitable for potential funding through a screening of Expressions of Interest. This study reports the research and development opportunities in such a project, the technical requirements and feasibility of its construction and operation, and the costs associated with the needed facilities and support activities. Transient Heat Transfer for Forced Convection Flow of Helium Gas. The group preparing this report consists of Michael McAshan at SSCL, Robert Behringer at Duke University, Katepalli Sreenivasan at Yale University, Xiao-Zhong Wu at Northern Illinois University and Russell Donnelly at the University of Oregon, who served as Editor for this report. This is a report prepared by a group interested in doing research in thermal convection using the large scale refrigeration facilities available at the SSC Laboratories (SSCL). More tips for preparing to attend Community Shred Day are available in the video below. In-Branch Shred Opportunities - maximum of 15 pounds per person.Community Shred Day events - maximum of two containers, 25-pound limit per container.Please follow shred limit guidelines below: Please avoid bringing magazines, newspapers, coupons or similar items that don't contain your sensitive information. What is a Community Shred-it Event Consumer fraud and identity theft are putting communities at risk. Participating branches include:ĭocuments recommended for shredding include anything that contains your identifying information, such as old checkbooks, credit card offers, account statements, etc. Please limit documents to shred at these locations to 15 pounds per person. Members can safely discard their unwanted, sensitive documents in locked bins located inside select branches during regular business hours. A maximum of two containers with a 25-pound limit per container will be accepted. Attendees are asked to bring documents in the cargo area of your vehicle, remain in your vehicle and enjoy the free, full-service event. Our Community Shred Day events are free and open to the public. Shredding services are provided by Shred-it. At our shredding events, we collect non-perishable food for the hungry, so please consider bringing a non-perishable food item to help those in need. Documents recommended for shredding include anything that contains your identifying information, such as old checkbooks, credit card offers, account statements, etc. We also offer free shredding events at locations across the state, where you can bring unwanted, confidential documents to be shredded one of the easiest ways to protect against identity theft. If authorization was denied pre-service or during concurrent review, follow appeal instructions on the notification letter. Wellcare By Allwell Medicare (MAPD, D-SNP & PPO)Īppeal: An Appeal is the mechanism which allows Providers the right to appeal actions of Wellcare By Allwell such as a pre-service prior authorization denial. PA Health and Wellness Attn: Reconsideration Note: if auth/medical necessity denial related, with records attached, will be routed to UM NOTE: Data stored on external storage devices such as USB devices, CD-R/W, DVD-R/W, or flash media will not be accepted.ĭetermination within 30 calendar days of receipt If there is a claim on file, please follow the process for Claim Reconsideration below. Note: appeals must be filed within 60 days of the notice of determination. Request within 90 calendar days from DOS. Note: If request for Retro-Auth exceeds 90 days from DOS, please see "Claim Reconsideration" Request P2P within 2 business days of date of denial Note: PHW will make 3 attempts to schedule prior to closing/upholding 2 call attempts by MD prior to closing/upholding Note: After initial auth, ongoing reviews are done via phone/faxįax: Submit ongoing records via fax/phone Non-Urgent: 2 business days of receipt of all necessary info, not to exceed 14 calendar daysįax: Follow fax submission directions located on the applicable form(s) Maternity admit: 1 business day with delivery outcome Observation (>23 hours hours): IP auth within 1 business dayĮR and post stabilization, urgent care, crisis intervention: 2 business days Observation (≤23 hours): one business day for non-par Community HealthChoices Medicaid ProcessĮmergent IP: within 24 hours or next business day This can include a request to reconsider authorization denials if an authorization was required and not obtained (justification should be included). Medical Necessity Appeal: If authorization or retro-authorization was denied, in part or whole, follow the Appeal process.Ĭlaim Reconsideration: Follow the claim reconsideration process if the claim did not pay as expected, but the claim does not need to be corrected. A decision will be made within 30 calendar days following receipt of request, not to exceed 90 calendar days from date of service. Requests for retrospective review must be submitted promptly. Participant was unconscious at presentation, Participant did not have their Medicaid ID card, or otherwise indicated Medicaid coverage, services authorized by another payer who subsequently determined participant was not eligible at the time of service). Retrospective Authorization Review: Retrospective review is an initial review of services provided to a Participant, but for which authorization and/or timely notification to PA Health & Wellness was not obtained due to extenuating circumstances (i.e. |
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